Diastereoisomers of l-proline-linked trityl-nitroxide biradicals: synthesis and effect of chiral configurations on exchange interactions

Author:

Zhai Weixiang12345,Feng Yalan12345,Liu Huiqiang12345,Rockenbauer Antal678910ORCID,Mance Deni1112131415,Li Shaoyong12345,Song Yuguang12345,Baldus Marc1112131415ORCID,Liu Yangping12345ORCID

Affiliation:

1. Tianjin Key Laboratory on Technologies Enabling Development of Clinical Therapeutics and Diagnostics

2. School of Pharmacy

3. Tianjin Medical University

4. Tianjin 300070

5. P. R. China

6. Institute of Materials and Environmental Chemistry

7. Hungarian Academy of Sciences

8. Department of Physics

9. Budapest University of Technology and Economics

10. 1111 Budapest

11. NMR Spectroscopy

12. Bijvoet Center for Biomolecular Research

13. Utrecht University

14. 3584 CH Utrecht

15. The Netherlands

Abstract

The chiral configuration of the two radical parts is a crucial factor controlling the exchange interactions and DNP properties of trityl-nitroxide biradicals.

Funder

National Natural Science Foundation of China

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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