Incorporation of coinage metal–NHC complexes into heptaphosphide clusters
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. Florida State University
3. Tallahassee
4. USA
5. Department of Cnmhemistry
6. Illinois Institute of Technology
7. Chicago
Abstract
A Me3Si-protected P7 cage reacts with N-heterocyclic-carbene complexes of coinage metals to yield a mononuclear Cu(i) complex featuring a Cu(η4-P7) core and a trinuclear Au(i) complex with linearly coordinated metal ions attached to the P7 cluster.
Funder
U.S. Department of Defense
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03119D
Reference49 articles.
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2. M. Shatruk , in Fundamentals and Applications of Phosphorus Nanomaterials , American Chemical Society , Washington, DC , 2019 , vol. 1333 , pp. 103–134
3. Polyphosphorus Compounds—New Results and Perspectives
4. P4 Activation by Main Group Elements and Compounds
5. P4 Activation by Late-Transition Metal Complexes
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