Incorporation of coinage metal–NHC complexes into heptaphosphide clusters-Reference-Cited by-同舟云学术

Incorporation of coinage metal–NHC complexes into heptaphosphide clusters

Published:2020 Issue:37 Volume:49 Page:12955-12959
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jo Minyoung¹²³⁴,Li Jingbai⁵⁶⁷⁴,Dragulescu-Andrasi Alina¹²³⁴,Rogachev Andrey Yu.⁵⁶⁷⁴,Shatruk Michael¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Florida State University

3. Tallahassee

4. USA

5. Department of Cnmhemistry

6. Illinois Institute of Technology

7. Chicago

Abstract

A Me₃Si-protected P₇ cage reacts with N-heterocyclic-carbene complexes of coinage metals to yield a mononuclear Cu(i) complex featuring a Cu(η⁴-P₇) core and a trinuclear Au(i) complex with linearly coordinated metal ions attached to the P₇ cluster.

Funder

U.S. Department of Defense

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT03119D

Reference49 articles.

1. R. Pöttgen , W.Hönle and H. G.von Schnering , in Encyclopedia of Inorganic Chemistry , ed. R. B. King , Wiley , Chichester , 2005 , vol. 8 , pp. 4255–4308

2. M. Shatruk , in Fundamentals and Applications of Phosphorus Nanomaterials , American Chemical Society , Washington, DC , 2019 , vol. 1333 , pp. 103–134

3. Polyphosphorus Compounds—New Results and Perspectives

4. P4 Activation by Main Group Elements and Compounds

5. P4 Activation by Late-Transition Metal Complexes

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