Rhodium complexes with planar-chiral cyclopentadienyl ligands: synthesis from <i>tert</i>-butylacetylene and catalytic performance in C–H activation of arylhydroxamates-Reference-Cited by-同舟云学术

Rhodium complexes with planar-chiral cyclopentadienyl ligands: synthesis from tert-butylacetylene and catalytic performance in C–H activation of arylhydroxamates

Published:2023 Issue:45 Volume:52 Page:17005-17010
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kolos Andrey V.¹^ORCID,Nelyubina Yulia V.¹²^ORCID,Podyacheva Evgeniya S.¹³,Perekalin Dmitry S.¹³^ORCID

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova str., Moscow, 119334, Russia

2. Moscow Institute of Physics and Technology, 9 Institutskiy per., Dolgoprudny, 141700, Russia

3. National Research University Higher School of Economics, 7 Vavilova str., Moscow, 117312, Russia

Abstract

Rhodium complexes with various planar-chiral cyclopentadienyl ligands were synthesized in 1–3 steps by the unusual 2 + 2 + 1-cyclotrimerization of tert-butylacetylene.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT03279E

Reference29 articles.

1. C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

2. Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

3. Electronic and Steric Tuning of a Prototypical Piano Stool Complex: Rh(III) Catalysis for C–H Functionalization

4. Chiral Cyclopentadienyl Ligands: Design, Syntheses, and Applications in Asymmetric Catalysis

5. Synthesis of catalytically active diene and cyclopentadienyl rhodium halide complexes

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