Planar-chiral arene ruthenium complexes: synthesis, separation of enantiomers, and application for catalytic C

Planar-chiral arene ruthenium complexes: synthesis, separation of enantiomers, and application for catalytic C–H activation

Published:2024 Issue:33 Volume:60 Page:4491-4494
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Boym Mikhail A.¹²,Pototskiy Roman A.¹,Podyacheva Evgeniya S.¹²,Chusov Denis A.¹²^ORCID,Nelyubina Yulia V.¹³,Perekalin Dmitry S.¹²^ORCID

Affiliation:

1. A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, 119334, Russia

2. National Research University Higher School of Economics, 7 Vavilova str., Moscow, 117312, Russia

3. Moscow Institute of Physics and Technology, 9 Institutskiy per., Dolgoprudny, 141700, Russia

Abstract

The enantiomers of an arene ruthenium complex were separated by chromatography using auxiliary chiral phosphine. The resolved planar-chiral complex catalyzed asymmetric C–H activation of N-methoxy-benzamides.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00181H

Reference36 articles.

1. C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

2. Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

3. Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

4. Chiral Cyclopentadienyl Ligands: Design, Syntheses, and Applications in Asymmetric Catalysis

5. Applications of Chiral Cyclopentadienyl (Cp x ) Metal Complexes in Asymmetric Catalysis

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1. H₈‐BINOL‐Derived Chiral η⁶‐Benzene Ligands: New Opportunities for the Ruthenium‐Catalyzed Asymmetric C−H Activation;Angewandte Chemie International Edition;2024-06-07

2. H₈‐BINOL‐Derived Chiral η⁶‐Benzene Ligands: New Opportunities for the Ruthenium‐Catalyzed Asymmetric C−H Activation;Angewandte Chemie;2024-06-07