A novel two-step Fe–Au type spin-crossover behavior in a Hofmann-type coordination complex {Fe(4-methylpyrimidine)2[Au(CN)2]2}
Author:
Affiliation:
1. Department of Chemistry
2. Toho University
3. Chiba 274-8510
4. Japan
5. Research Centre for Materials with Integrated Properties
Abstract
A Hofmann-type two-step spin-crossover (SCO) complex with a pyrimidine derivative ligand was synthesized.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01681K
Reference42 articles.
1. Thermal and light induced spin crossover in a mononuclear iron(II) complex
2. Pressure-Induced Spin-Crossover Features at Variable Temperature Revealed by In Situ Synchrotron Powder X-ray Diffraction
3. Guest Molecule Inserted Spin Crossover Complexes: Fe[4-(3-Pentyl)pyridine]2[Au(CN)2]2·Guest
4. Guest Induced Strong Cooperative One- and Two-Step Spin Transitions in Highly Porous Iron(II) Hofmann-Type Metal–Organic Frameworks
5. Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal
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