Soma–Iwamoto-type SCO complex Fe(quinazoline)2[Au(CN)2]2 using the quinazoline-type ligand-Reference-Cited by-同舟云学术

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Soma–Iwamoto-type SCO complex Fe(quinazoline)₂[Au(CN)₂]₂ using the quinazoline-type ligand

Published:2024 Issue:22 Volume:53 Page:9248-9251
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kitase Kosuke¹^ORCID,Akahoshi Daisuke²,Kitazawa Takafumi¹³

Affiliation:

1. Department of Chemistry, Toho University, Chiba 274-8510, Japan

2. Department of Physics, Toho University, Chiba 274-8510, Japan

3. Research Centre for Materials with Integrated Properties, Toho University, Chiba 274-8510, Japan

Abstract

We have synthesized Fe(quinazoline)2[Au(CN)2]2 (1). Complex 1 shows the Soma–Iwamoto-type bilayer and a spin-crossover (SCO) phenomenon. Mononuclear complex with a hydrogen-bonding network Fe(H2O)2(quinazoline)2[Au(CN)2]2 has also been obtained.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00458B

Reference18 articles.

1. Verbindungen von Kohlenwasserstoffen mit Metallsalzen

2. Spin-crossover behaviour of the coordination polymer FeII(C5H5N)2NiII(CN)4

3. Three-Dimensional Interpenetrating Double and Triple Framework Structures in[Cd(bpy)2{Ag(CN)2}2] and[Cd(pyrz){Ag2(CN)3}{Ag(CN)2}]

4. Variations of multi-dimensional supramolecular structures built of the two-dimensional [Cd(py)2{Ag(CN)2}2] n network: Three-dimensional textile structures of catena-poly[trans-bis(pyridine)cadmium(II)-di-?-{dicyanoargentato(I)-N,N?}�G (G = benzene or pyrrole) and two-dimensional layer structure of catena-poly[trans-bis(pyridine)cadmium(II)-di-?-{dicyanoargentato(I)-N,N?}]

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