ATRA-like alkylation–peroxidation of alkenes with trichloromethyl derivatives by the combination of tBuOOH and NEt3
Author:
Affiliation:
1. College of Chemical Engineering
2. Guangdong University of Petrochemical Technology
3. Maoming 525000
4. P. R. China
5. School of Chemistry and Material Engineering
6. Huizhou University
7. Huizhou 516007
8. China
Abstract
This protocol provides a unique and innovative approach to the construction of α-tert-butylperoxy-β-dichloromethyl alkanes, employing CHCl3 as an alkylating reagent to provide a –CHCl2 group, and TBHP as an oxidant to provide an α-tBuOO group.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00868J
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