ACdCO3F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction-Reference-Cited by-同舟云学术

ACdCO3F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction

Published:2015 Issue:103 Volume:5 Page:84754-84761
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Zou Guohong¹²³⁴,Nam Gnu¹⁵⁶⁴,Kim Hyung Gu¹²³⁴,Jo Hongil¹²³⁴,You Tae-Soo¹⁵⁶⁴,Ok Kang Min¹²³⁴

Affiliation:

1. Department of Chemistry

2. Chung-Ang University

3. Seoul

4. Republic of Korea

5. Chungbuk National University

6. Cheongju

Abstract

The remarkably large SHG efficiency of KCdCO₃F originates from enhancement via interatomic interactions between the s and p states of Cd²⁺ and the π-conjugated groups of the [CO₃]²⁻ unit.

Funder

National Research Foundation of Korea

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA17209H

Reference65 articles.

1. Noncentrosymmetric Oxides

2. Combining Second-Order Jahn−Teller Distorted Cations to Create Highly Efficient SHG Materials: Synthesis, Characterization, and NLO Properties of BaTeM2O9 (M = Mo6+ or W6+)

3. Structural Modulation of Molybdenyl Iodate Architectures by Alkali Metal Cations in AMoO3(IO3) (A = K, Rb, Cs): A Facile Route to New Polar Materials with Large SHG Responses

4. Hydrogen-Bonded Ferroelectrics Based on Metal−Organic Coordination

5. Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A = K, Rb) as UV Nonlinear Optical Crystals

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