Palladium-catalyzed [6 + 4] cycloaddition with π-allyl all-carbon 1,6-dipole for the synthesis of ten-membered heterocycles-Reference-Cited by-同舟云学术

Palladium-catalyzed [6 + 4] cycloaddition with π-allyl all-carbon 1,6-dipole for the synthesis of ten-membered heterocycles

Published:2024 Issue: Volume: Page:
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Jun-Tao¹²,Lin Na¹,Xu Linli¹,Wang Yi²,Luo Xiaoyan²^ORCID,Liu Yang-Zi¹^ORCID,Deng Wei-Ping¹²^ORCID

Affiliation:

1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Department of Chemistry, Zhejiang Normal University, 688 Yingbin Road, Jinhua, 321004, P. R. China

2. Shanghai Frontiers Science Center of Optogenetic Techniques for Cell Metabolism, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, P. R. China

Abstract

This work introduces a novel α,α-diester-δ-vinylvalerolactone as a dipolar precursor in a palladium-catalyzed [6 + 4] cycloaddition reaction with azadienes, resulting in the production of ten-membered heterocycles.

Funder

Zhejiang Normal University

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D3QO01793A

Reference53 articles.

1. Novel indole alkaloids from cell suspension cultures of aspidosperma quebracho blanco schlecht