Orbital energy mismatch engenders high-spin ground states in heterobimetallic complexes
Author:
Affiliation:
1. Department of Chemistry
2. Northwestern University
3. Evanston
4. USA
5. University of South Dakota
6. Vermillion
7. Advanced Photon Source
8. Argonne National Laboratory
9. Lemont
Abstract
We report a series of high spin bimetallic transition metal–tin complexes. The unusual high spin configuration in a bimetallic complex is enabled by an energetic mismatch in the orbital energies, leading to lanthanide-like nonbonding interactions.
Funder
U.S. Department of Energy
Air Force Office of Scientific Research
National Science Foundation
American Chemical Society Petroleum Research Fund
Northwestern University
Canadian Light Source
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC03777J
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