Spin−Orbit Coupling in the Oxidative Activation of H−H by FeO+. Selection Rules and Reactivity Effects
Author:
Affiliation:
1. Contribution from The Institute of Chemistry and The Minerva Center of Computational Quantum Chemistry, The Hebrew University, 91904 Jerusalem, Israel
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja963033g
Reference53 articles.
1. CH and CC Bond Activation by Bare Transition-Metal Oxide Cations in the Gas Phase
2. Surprisingly low reactivity of bare iron monoxide ion (FeO+) in its spin-allowed, highly exothermic reaction with molecular hydrogen to generate iron(1+) and water
3. Stoichiometric Gas-Phase Oxidation Reactions of CoO+ with Molecular Hydrogen, Methane, and Small Alkanes
4. State-Specific Reactions of Fe+(a6D,a4F) with D2O and Reactions of FeO+ with D2
5. Conversion of CH4 to CH3OH: Reactions of CoO+ with CH4 and D2, Co+ with CH3OD and D2O, and Co+(CH3OD) with Xe
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