Palladium-catalyzed addition of acylsilanes across alkynes<i>via</i>the activation of a C

Palladium-catalyzed addition of acylsilanes across alkynesviathe activation of a C–Si bond

Published:2023 Issue:10 Volume:14 Page:2706-2712
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Inagaki Tetsuya¹,Ando Takahiro¹,Sakurai Shun¹,Yamanaka Masahiro²^ORCID,Tobisu Mamoru¹³^ORCID

Affiliation:

1. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Osaka, Japan

2. Department of Chemistry and Research Center for Smart Molecules, Faculty of Science, Rikkyo University, Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan

3. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI) Suita, Osaka 565-0871, Japan

Abstract

Palladium-catalyzed addition of a C–Si bond in acylsilanes across the triple bonds in an alkyne bearing a carbonyl group at one terminal is reported.

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00181D

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