Palladium-Catalyzed Addition of Trifluoroacetylsilanes to Alkenes and Allenes via the Cleavage of C

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Palladium-Catalyzed Addition of Trifluoroacetylsilanes to Alkenes and Allenes via the Cleavage of C–Si Bonds

Published:2024-03-05 Issue:10 Volume:26 Page:2141-2145
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Inagaki Tetsuya¹,Akita Yuki¹,Tobisu Mamoru¹²^ORCID

Affiliation:

1. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan

2. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, Suita, Osaka 565-0871, Japan

Funder

Japan Society for the Promotion of Science

Publisher

American Chemical Society (ACS)

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.4c00595

Reference28 articles.

1. Acylsilanes: valuable organosilicon reagents in organic synthesis

2. Silicon‐Derived Singlet Nucleophilic Carbene Reagents in Organic Synthesis

3. Visible-Light-Induced In Situ Generation of Fischer-Type Copper Carbene Complexes from Acylsilanes and Its Application to Catalytic [4 + 1] Cycloaddition with Siloxydienes

4. Photoinduced Copper-Catalyzed Asymmetric Acylation of Allylic Phosphates with Acylsilanes

5. Cu/ Sa Box‐Catalyzed Photoinduced Coupling of Acylsilanes with Alkynes

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