Promotion of TH3 (T = Si and Ge) group transfer within a tetrel bond by a cation

Promotion of TH3 (T = Si and Ge) group transfer within a tetrel bond by a cation–π interaction

Published:2022 Issue:2 Volume:24 Page:1113-1119
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Liu Na¹,Wu Qiaozhuo¹,Li Qingzhong¹^ORCID,Scheiner Steve²^ORCID

Affiliation:

1. The Laboratory of Theoretical and Computational Chemistry, School of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, People's Republic of China

2. Department of Chemistry and Biochemistry, Utah State University, Logan, UT 84322-0300, USA

Abstract

A TH3 group transfer is promoted by adding a cation–π interaction in the PhTH3 binary systems.

Funder

Natural Science Foundation of Shandong Province

National Science Foundation

Yantai University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP05323J

Reference61 articles.

1. All-Visible-Light-Activated Dithienylethenes Induced by Intramolecular Proton Transfer

2. Proton Transfer Mechanisms in Bimetallic Hydrogenases

3. Nuclear Quantum Effects Largely Influence Molecular Dissociation and Proton Transfer in Liquid Water under an Electric Field

4. Excited-state intramolecular proton transfer in the kinetic-control regime

5. Mechanism of the formation of proton transfer pathways in photosynthetic reaction centers

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