Enhancement of tetrel bond involving tetrazole-TtR<sub>3</sub> (Tt = C, Si; R = H, F). Promotion of SiR<sub>3</sub> transfer by a triel bond-Reference-Cited by-同舟云学术

Enhancement of tetrel bond involving tetrazole-TtR₃ (Tt = C, Si; R = H, F). Promotion of SiR₃ transfer by a triel bond

Published:2022 Issue:42 Volume:24 Page:25895-25903
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wu Qiaozhuo¹,Xie Xiaoying¹,Li Qingzhong¹^ORCID,Scheiner Steve²^ORCID

Affiliation:

1. The Laboratory of Theoretical and Computational Chemistry, School of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, P. R. China

2. Department of Chemistry and Biochemistry, Utah State University, Logan, UT 84322-0300, USA

Abstract

The combination of a CR3 (R = H, F) with a tetrazole can result in a moderate carbon bond, which can be further strengthened by a triel bond. On the other hand, SiR3 group is half transferred between the two N atoms in these conditions.

Funder

Natural Science Foundation of Shandong Province

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP04194D

Reference72 articles.

1. Design of Lead(II) Metal-Organic Frameworks Based on Covalent and Tetrel Bonding

2. Importance of π-Interactions Involving Chelate Rings in Addition to the Tetrel Bonds in Crystal Engineering: A Combined Experimental and Theoretical Study on a Series of Hemi- and Holodirected Nickel(II)/Lead(II) Complexes