π-Adsorption promoted electrocatalytic acetylene semihydrogenation on single-atom Ni dispersed N-doped carbon-Reference-Cited by-同舟云学术

π-Adsorption promoted electrocatalytic acetylene semihydrogenation on single-atom Ni dispersed N-doped carbon

Published:2022 Issue: Volume: Page:
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Ma Wenxiu¹,Chen Zhe²^ORCID,Bu Jun¹,Liu Zhenpeng¹,Li Jinjin¹,Yan Chen¹,Cheng Lin³,Zhang Lei¹,Zhang Hepeng¹^ORCID,Zhang Jichao⁴,Wang Tao²,Zhang Jian¹^ORCID

Affiliation:

1. Key Laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an, 710129, P. R. China

2. Center of Artificial Photosynthesis for Solar Fuels, School of Science, Westlake University, Hangzhou 310024, P. R. China

3. School of Science, Xi'an Polytechnic University, Xi'an, 710048, P. R. China

4. Shanghai Synchrotron Radiation Facility, Zhangjiang Laboratory, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai, 201204, P. R. China

Abstract

As a novel electrocatalyst for acetylene semihydrogenation, single-atom nickel dispersed N-doped carbon exhibits a high acetylene conversion of 97.4%, which are attributed to weak π-adsorption of ethylene on individual Ni sites.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shaanxi Province

Fundamental Research Funds for the Central Universities

Northwestern Polytechnical University

Westlake University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TA/D1TA08002D