Synthesis, electronic nature, and reactivity of selected silylene carbonyl complexes-Reference-Cited by-同舟云学术

Synthesis, electronic nature, and reactivity of selected silylene carbonyl complexes

Published:2022 Issue:21 Volume:51 Page:8249-8257
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schoening Juliane¹,Ganesamoorthy Chelladurai¹,Wölper Christoph¹,Solel Ephrath²^ORCID,Schreiner Peter R.²³^ORCID,Schulz Stephan¹⁴^ORCID

Affiliation:

1. Inorganic Chemistry, University of Duisburg-Essen, Universitätsstr. 7, 45141 Essen, Germany

2. Institute of Organic Chemistry, Justus Liebig University, Heinrich-Buff-Ring 17, D-35392 Giessen, Germany

3. Center for Materials Research (LaMa), Justus Liebig University, Heinrich-Buff-Ring 16, 35392 Giessen, Germany

4. Center for Nanointegration Duisburg-Essen (Cenide), University of Duisburg-Essen, Carl-Benz-Straße 199, 47057 Duisburg, Germany

Abstract

We report on the syntheses and single crystal X-ray structures of rare room-temperature stable silylene carbonyl complexes [L(X)Ga]2Si-CO, the influence of the substituent X on their electronic nature and their promising potential in NH3 activation.

Funder

University of Duisburg-Essen

Justus Liebig University Giessen

Alexander von Humboldt-Stiftung/Foundation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01335E

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