Catalytic hydroboration of aldehydes and ketones with an electron-rich acyclic metallasilylene-Reference-Cited by-同舟云学术

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Catalytic hydroboration of aldehydes and ketones with an electron-rich acyclic metallasilylene

Published:2024 Issue:11 Volume:15 Page:4161-4170
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kapp Leon¹,Wölper Christoph¹,Siera Hannah²^ORCID,Haberhauer Gebhard²^ORCID,Schulz Stephan¹³^ORCID

Affiliation:

1. Institute for Inorganic Chemistry, University of Duisburg-Essen, Universitätsstraße 5–7, 45117 Essen, Germany

2. Institute for Organic Chemistry, University of Duisburg-Essen, Universitätsstraße 5–7, 45117 Essen, Germany

3. Center for Nanointegration Duisburg-Essen (Cenide), University of Duisburg-Essen, Carl-Be, Germany

Abstract

Catalytic hydroboration of aldehydes and ketones is achieved with alkoxysilylene 2. Quantum chemical calculations gave insights into the energetics of its formation and provide possible catalytic reaction mechanism.

Funder

Deutsche Forschungsgemeinschaft

Universität Duisburg-Essen

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06842K

Reference85 articles.

1. H. C.Brown , In Hydroboration , W. A. Benjamin Inc. , New York , 1962 , pp. 1–38

2. Hydroborations catalysed by transition metal complexes

3. Twenty-five years of bis-pentafluorophenyl borane: a versatile reagent for catalyst and materials synthesis

4. Catalytic Hydroboration with Rhodium Complexes

5. The Hidden Role of Boranes and Borohydrides in Hydroboration Catalysis

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