Highly regio- and diastereoselective Cu-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes with B2pin2 and PhMe2Si–Bpin
Author:
Affiliation:
1. Shanghai Key Laboratory of Chemical Biology
2. School of Pharmacy
3. East China University of Science and Technology (ECUST)
4. Shanghai 200237
5. China
Abstract
An efficient method for the synthesis of trans-difluorocyclopropyl boronates and silanes through a Cu-catalyzed hydroborylation and hydrosilylation of difluorocyclopropenes was reported.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00580C
Reference54 articles.
1. Biosynthesis and Metabolism of Cyclopropane Rings in Natural Compounds
2. Bonding Properties of Cyclopropane and Their Chemical Consequences
3. Application of oxygen/nitrogen substituted donor-acceptor cyclopropanes in the total synthesis of natural products
4. Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis
5. Recent advances in the total synthesis of cyclopropane-containing natural products
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