Hydrocarbon oxidation by iron-porphyrin immobilized on SBA-15 as biomimetic catalyst: role of silica surface-Reference-Cited by-同舟云学术

Hydrocarbon oxidation by iron-porphyrin immobilized on SBA-15 as biomimetic catalyst: role of silica surface

Published:2016 Issue:106 Volume:6 Page:104886-104896
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Zanatta L. D.¹²³⁴⁵,Barbosa I. A.¹²³⁴⁵,Zanardi F. B.¹²³⁴⁵,de Sousa Filho P. C.¹²³⁴⁵,Bolzon L. B.⁶⁷⁸⁹¹⁰,Ramos A. P.¹²³⁴⁵,Serra O. A.¹²³⁴⁵,Iamamoto Y.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Faculdade de Filosofia

3. Ciências e Letras de Ribeirão Preto

4. University of São Paulo

5. Ribeirão Preto

6. Department of General and Inorganic Chemistry

7. Institute of Chemistry

8. Federal University of Bahia

9. Salvador

10. Brazil

Abstract

We describe a heterogeneous catalyst containing iron-porphyrins in SBA-15 structures for biomimetic catalysis, correlating surface adsorption/wetting characteristics to oxidation mechanisms.

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

São Paulo Research Foundation

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA18395F

Reference63 articles.

1. First industrial-scale biomimetic oxidation of hydrocarbon with air over metalloporphyrins as cytochrome P-450 monooxygenase model and its mechanistic studies