Investigating deposition sequence during synthesis of Pd/Al2O3 catalysts modified with organic monolayers

Author:

Blanchette Zachary1ORCID,Zhang Jing1ORCID,Yazdi Sadegh23ORCID,Griffin Michael B.4ORCID,Schwartz Daniel K.1ORCID,Medlin J. Will1ORCID

Affiliation:

1. Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80303, USA

2. Renewable & Sustainable Energy Institute, University of Colorado, Boulder, Colorado 80309, USA

3. Materials Science & Engineering Program, University of Colorado, Boulder, Colorado 80309, USA

4. Catalytic Carbon Transformation and Scale-up Center, National Renewable Energy Lab, Golden, Colorado 80401, USA

Abstract

Pd/Al2O3 catalysts were modified with phosphonic acids through “metal-first” and “SAM-first” deposition sequences and evaluated for benzyl alcohol hydrodeoxygenation performance. SAM-first catalysts exhibited higher mass activities.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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