Ruthenium single-atom doping-driven modulation of Co3O4 spinel tetrahedral site 3d-orbital occupancy in lithium–oxygen batteries

Author:

Fan Yining1,Li Ting1,Li Bin1,Hu Anjun1ORCID,Li Dongfen2,Li Kun1,Yang Borui1,Pan Yu1,Liu Jing1,Long Jianping1ORCID

Affiliation:

1. College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, 1#, Dongsanlu, Erxianqiao, Chengdu 610059, Sichuan, P. R. China

2. College of Computer Science and Cyber Security, Chengdu University of Technology, 1#, Dongsanlu, Erxianqiao, Chengdu 610059, Sichuan, P. R. China

Abstract

This work reveals theoretically and experimentally the internal mechanism of using Ru single atoms to control the electronic structure of tetrahedral sites in spinel Co3O4 to catalyze the operation of lithium–oxygen batteries (LOBs).

Funder

National Natural Science Foundation of China

Chengdu University of Technology

Publisher

Royal Society of Chemistry (RSC)

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