Rhodium(iii)-catalyzed C–H activation/[4+3] annulation of N-phenoxyacetamides and α,β-unsaturated aldehydes: an efficient route to 1,2-oxazepines at room temperature-Reference-Cited by-同舟云学术

Rhodium(iii)-catalyzed C–H activation/[4+3] annulation of N-phenoxyacetamides and α,β-unsaturated aldehydes: an efficient route to 1,2-oxazepines at room temperature

Published:2014 Issue:81 Volume:50 Page:12135-12138
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Duan Pingping¹²³⁴,Lan Xia¹²³⁴,Chen Ying¹²³⁴,Qian Shao-Song⁵⁶⁷,Li Jie Jack⁸⁹¹⁰,Lu Liang¹¹⁵¹²¹³¹⁴,Lu Yanbo¹²³⁴,Chen Bo¹²³⁴,Hong Mei¹²³⁴,Zhao Jing¹²³⁴¹¹

Affiliation:

1. Shenzhen Key Lab of Nano-Micro Material Research

2. School of Chemical Biology and Biotechnology

3. Shenzhen Graduate School of Peking University

4. Shenzhen, China

5. School of Life Sciences

6. Shandong University of Technology

7. Zibo 255049, China

8. Department of Chemistry

9. University of San Francisco

10. San Francisco 94117-1080, USA

11. State Key Laboratory of Pharmaceutical Biotechnology

12. Institute of Chemistry and BioMedical Sciences

13. Nanjing University

14. Nanjing, China

Abstract

Rhodium-catalyzed C–H bond functionalization led to a [4+3] annulation strategy to access 1,2-oxazepine rings.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC05485G

Reference57 articles.

1. Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

2. Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

3. Towards mild metal-catalyzed C–H bond activation

4. Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

5. Cu–Rh Redox Relay Catalysts for Synthesis of Azaheterocycles via C–H Functionalization

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