Heterometallic aluminates: alkali metals trapped by an aluminium aryloxide claw

Author:

Muñoz Mª Teresa123,Cuenca Tomás123,Mosquera Marta E. G.123

Affiliation:

1. Departamento de Química Orgánica y Química Inorgánica

2. Universidad de Alcalá

3. E-28871 Alcalá de Henares, Spain

Abstract

In the heterometallic species prepared [AlMMe2{2,6-(MeO)2C6H3O}2]n (M = Li, Na and K), the {AlMe2{(2,6-(MeO)2C6H3O}2} moiety acts as a claw that grasps alkali metals of very different sizes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference85 articles.

1. T. Taguchi and H.Yanai , Al(III) Lewis acids , in Acid catalysis in modern organic synthesis , ed. H. Yamamoto and K. Ishihara , Wiley , Weinheim , 2008

2. S. Woodward and S.Dagorne , Modern Organoaluminum Reagents , Springer , 2012

3. An Aluminum Ate Base:  Its Design, Structure, Function, and Reaction Mechanism

4. A study of Noyori's reagent

5. Designer Lewis acid catalysts—bulky aluminium reagents for selective organic synthesis

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