Homolysis/mesolysis of alkoxyamines activated by chemical oxidation and photochemical-triggered radical reactions at room temperature-Reference-Cited by-同舟云学术

Homolysis/mesolysis of alkoxyamines activated by chemical oxidation and photochemical-triggered radical reactions at room temperature

Published:2021 Issue:23 Volume:8 Page:6561-6576
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Audran Gérard¹,Blyth Mitchell T.²^ORCID,Coote Michelle L.²^ORCID,Gescheidt Georg³^ORCID,Hardy Micael¹,Havot Jeffrey¹,Holzritter Maxence¹,Jacoutot Samuel¹,Joly Jean-Patrick¹,Marque Sylvain R. A.¹^ORCID,Koumba Tataye Moussounda Moussounda¹,Neshchadin Dmytro³^ORCID,Vaiedelich Enzo¹

Affiliation:

1. Aix Marseille Univ, CNRS, ICR, UMR 7273, Case 551, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France

2. Research School of Chemistry, Australian National University, Canberra, ACT 2601, Australia

3. Institute of Physical and Theoretical Chemistry, TU Graz, Stremayrgasse 9/Z2, A-8010 Graz, Austria

Abstract

Instantaneous and spontaneous room temperature C–ON bond mesolysis of alkoxyamines triggered by chemical oxidation.

Funder

Centre National de la Recherche Scientifique

Agence Nationale de la Recherche

Australian Research Council

Aix-Marseille Université

Campus France

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO01276B

Reference57 articles.

1. Alkoxyamines: a new family of pro-drugs against cancer. Concept for theranostics

2. Chemically Triggered C–ON Bond Homolysis of Alkoxyamines. Quaternization of the Alkyl Fragment

3. C–ON bond homolysis of alkoxyamines triggered by paramagnetic copper(ii) salts

4. Switching radical stability by pH-induced orbital conversion

5. Computational design of pH-switchable control agents for nitroxide mediated polymerization

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