C–ON bond homolysis of alkoxyamines triggered by paramagnetic copper(ii) salts-Reference-Cited by-同舟云学术

C–ON bond homolysis of alkoxyamines triggered by paramagnetic copper(ii) salts

Published:2016 Issue:11 Volume:3 Page:1464-1472
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Audran Gérard¹²³⁴⁵,Bagryanskaya Elena⁶⁷⁸,Bagryanskaya Irina⁶⁷⁸,Brémond Paul¹²³⁴⁵,Edeleva Mariya⁶⁷⁸,Marque Sylvain R. A.¹²³⁴⁵,Parkhomenko Dmitriy⁶⁷⁸^ORCID,Tretyakov Evgeny⁶⁷⁸,Zhivetyeva Svetlana⁶⁷⁸

Affiliation:

1. Aix Marseille Univ

2. CNRS

3. ICR

4. UMR 7273

5. case 551

6. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS

7. 630090 Novosibirsk

8. Russia

Abstract

Pyridine-based alkoxyamines were used as ligands for Cu(hfac)₂ to prepare the first metallic complexes of alkoxyamines. Structures of complexes were determined by X-ray analysis and a 21-fold increase in the C–ON bond homolysis was observed.

Funder

Agence Nationale de la Recherche

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QI/C6QI00277C

Reference28 articles.

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