Cu-catalyzed cycloaddition of aryl azides to 1-iodobuta-1,3-diynes: an experimental and quantum chemical study of unusual regiochemistry-Reference-Cited by-同舟云学术

Cu-catalyzed cycloaddition of aryl azides to 1-iodobuta-1,3-diynes: an experimental and quantum chemical study of unusual regiochemistry

Published:2024 Issue:11 Volume:48 Page:4831-4845
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Govdi Anastasia I.¹^ORCID,Danilkina Natalia A.¹^ORCID,Shtyrov Andrey A.¹²^ORCID,Ryazantsev Mikhail N.¹^ORCID,Kim Mia D.¹^ORCID,Kryukova Mariya A.¹,Balova Irina A.¹^ORCID

Affiliation:

1. Institute of Chemistry, Saint Petersburg University (SPbU), Universitetskaya nab. 7/9, 199034, Saint Petersburg, Russia

2. Nanotechnology Research and Education Centre RAS, Saint Petersburg Academic University, Khlopina Street 8/3, 194021, Saint Petersburg, Russia

Abstract

The nontrivial CuAAC regiochemistry of aryl azides and 1-iodobutadiynes helped to establish the binuclear character of the CuAAC mechanism for iodoalkynes.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D3NJ03823H

Reference72 articles.

1. The Huisgen Reaction: Milestones of the 1,3‐Dipolar Cycloaddition

2. The 1,3‐Dipolar Cycloaddition: From Conception to Quantum Chemical Design

3. 1.3‐Dipolare Cycloadditionen, XXXII. Kinetik der Additionen organischer Azide an CC‐Mehrfachbindungen

4. A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes

5. Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides

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