Structural evolution of iron forming iron oxide in a deep eutectic-solvothermal reaction

Author:

Hammond Oliver S.1234ORCID,Atri Ria S.12345ORCID,Bowron Daniel T.67894,de Campo Liliana101112,Diaz-Moreno Sofia131415164,Keenan Luke L.131415164,Doutch James67894,Eslava Salvador517184ORCID,Edler Karen J.1234ORCID

Affiliation:

1. Department of Chemistry and Centre for Doctoral Training in Sustainable Chemical Technologies

2. University of Bath

3. Bath BA2 7AY

4. UK

5. Department of Chemical Engineering

6. ISIS Neutron and Muon Source

7. Science and Technology Facilities Council

8. Rutherford Appleton Laboratory

9. Didcot OX11 0QX

10. Australian Centre for Neutron Scattering

11. ANSTO

12. Australia

13. Diamond Light Source

14. Diamond House

15. Harwell Science and Innovation Campus

16. Didcot, Oxfordshire, OX11 0DE

17. Imperial College London

18. London SW7 2AZ

Abstract

Iron oxide nanoparticle formation in DES was studied in situ across multiple length scales. Initial chloride-containing iron complexes react to form oxygen-rich species which precipitate. Morphology and growth time are defined by solvent composition.

Funder

University of Bath

Engineering and Physical Sciences Research Council

Science and Technology Facilities Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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