Singlet exciton and singlet/triplet self-trapped excitons for ultra-broadband white-light emission in a zero-dimensional cadmium bromide hybrid

Author:

Gao Huizhi1,Lu Zhuoya1,Zhao Xingxing1,Zhang Ke1,Zhu Xudong23,Cheng Rixin1,Li Shi-Li1,Qi Zhikai1ORCID,Zhang Xian-Ming14

Affiliation:

1. Key Laboratory of Magnetic Molecules & Magnetic Information Materials (Ministry of Education), School of Chemistry & Material Science, Shanxi Normal University, Taiyuan 030032, P. R. China

2. CAS Key Laboratory of Quantum Information, University of Science and Technology of China, Hefei, Anhui, 230026, China

3. Institute of Artificial Intelligence, Hefei Comprehensive National Science Center, Hefei, Anhui, 230026, China

4. Key Laboratory of Interface Science and Engineering in Advanced Material (Ministry of Education), College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China

Abstract

A new zero-dimensional hybrid Cd-based metal halide featuring isolated CdBr4 tetrahedra segregated by luminescent organic templates shows UV-excited ultra-broadband white light emission with a CRI of 98 and a PLQY of 23.46%.

Funder

National Natural Science Foundation of China

Fund for Shanxi Key Subjects Construction

Shanxi Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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