Influence of picolinate ancillary ligands on unique photophysical properties of Ir(ppz)2(LX)

Author:

Kim Daehoon1,Ahn Mina1,Wee Kyung-Ryang1ORCID,Cho Dae Won2ORCID

Affiliation:

1. Department of Chemistry, Daegu University, Gyeongsan 38453, Republic of Korea

2. Center for Photovoltaic Materials, Korea University, Sejong Campus, Sejong 30019, Korea

Abstract

Comparing to Ir(ppz)3, Ir(ppz)2(LX) emits a red-shifted phosphorescence of caused by an interligand energy transfer between the ppz and LX ligands. Especially, Ir(ppz)2(picOH) showed an intramolecular proton transfer in the excited singlet state.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference24 articles.

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2. Highly Efficient OLEDs with Phosphorescent Materials , ed. H. Yersin , Wiley-VCH , Berlin , 2007

3. Electroluminescent materials for white organic light emitting diodes

4. Blue and Near-UV Phosphorescence from Iridium Complexes with Cyclometalated Pyrazolyl or N-Heterocyclic Carbene Ligands

5. Synthesis and Characterization of Facial and Meridional Tris-cyclometalated Iridium(III) Complexes

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