Positional isomeric effect on the structural variation of Cd(ii) coordination polymers based on flexible linear/V-shaped bipyridyl benzene ligands
Author:
Affiliation:
1. College of Chemistry and Chemical Engineering
2. Anyang Normal University
3. Anyang 455000, PR China
4. Luoyang Normal University
5. Luoyang 471022, PR China
Abstract
Solvothermal reactions of Cd(OAc)2·2H2O with 2,2′-azodibenzoic acid and five positional isomeric N-donor bipyridyl benzene ligands in MeOH/H2O at 170 °C gave rise to five coordination polymers. Complexes 1–5 were characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction, and single-crystal X-ray diffraction.
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CE/C4CE01856G
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