Unprecedented iminobenzosemiquinone and iminobenzoquinone coordinated mononuclear Cu(ii) complex formation under air-Reference-Cited by-同舟云学术

Unprecedented iminobenzosemiquinone and iminobenzoquinone coordinated mononuclear Cu(ii) complex formation under air

Published:2015 Issue:20 Volume:44 Page:9375-9381
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mondal Manas Kumar¹²³⁴,Biswas Abul Kalam⁵⁶⁷⁴,Ganguly Bishwajit⁵⁶⁷⁴,Mukherjee Chandan¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology

3. Guwahati

4. India

5. Computation and Simulation Unit (Analytical Discipline and Centralized Instrument Facility)

6. CSIR–Central Salt and Marine Chemicals Research Institute

7. Bhavnagar-364002

Abstract

Ligand H4LS(AP/AP) comprised of two orthogonally placed non-innocent unit that were bridged by a common -ortho S atom. It reacted with CuCl₂·2H₂O and provided a mononuclear diamagnetic Cu(ii) complex where two non-innocent units were in two different oxidation states.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03263B

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