Low-spin [MII(L)2] and [MIII(L)2]+ (M = Fe and Co) complexes of tridentate azo-containing pyridine/pyrazine amide ligands: structures, properties and redox potential correlations

Author:

Sengupta Arunava1234,Rajput Amit1234,Barman Suman K.1234,Mukherjee Rabindranath1234ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kanpur

3. Kanpur 208 016

4. India

Abstract

Comparative molecular (X-ray) and electronic (DFT, TD-DFT) structural studies have been done; the E1/2 values (MIII/MII couple) for Fe, Co and Ni complexes linearly correlate with other low-spin complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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