Predictable electronic tuning of FeII and RuII complexes via choice of azine: correlation of ligand pKa with Epa(MIII/II) of complex-Reference-Cited by-同舟云学术

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Predictable electronic tuning of Fe^II and Ru^II complexes via choice of azine: correlation of ligand pK_a with E_pa(M^III/II) of complex

Published:2024 Issue:5 Volume:53 Page:1999-2007
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Robb Matthew G.¹^ORCID,Bondì Luca¹,Rodríguez-Jiménez Santiago¹,Garden Anna L.¹^ORCID,Jerabek Paul²^ORCID,Brooker Sally¹^ORCID

Affiliation:

1. Department of Chemistry and MacDiarmid Institute of Advanced Materials and Nanotechnology, University of Otago, P. O. Box 56, Dunedin 9054, New Zealand

2. Institute of Hydrogen Technology, Helmholtz Zentrum Hereon, Max Planck-Straße 1, 21502 Geesthacht, Germany

Abstract

Strong linear correlations are seen for FeII and RuII families of [M(Lazine)3]2+, between observed E(MIII/II) and DFT calculated HOMO energy or ionisation potential of [M(Lazine)3]2+, or with easily calculated pKa value of Lazine.

Funder

MacDiarmid Institute for Advanced Materials and Nanotechnology

University of Otago

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03484D

Reference64 articles.

1. Metal complex sensitizers in dye-sensitized solar cells

2. Aqueous dye-sensitized solar cells

3. Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

4. Making Oxygen with Ruthenium Complexes

5. Biological applications of Ru(II) polypyridyl complexes

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