Atomically dispersed cobalt on graphitic carbon nitride as a robust catalyst for selective oxidation of ethylbenzene by peroxymonosulfate-Reference-Cited by-同舟云学术

Atomically dispersed cobalt on graphitic carbon nitride as a robust catalyst for selective oxidation of ethylbenzene by peroxymonosulfate

Published:2021 Issue:5 Volume:9 Page:3029-3035
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Li Jiaquan¹²³⁴,Zhao Shiyong¹²³⁴,Yang Shi-Ze⁵⁶⁷⁸,Wang Shaobin⁹¹⁰¹¹⁴^ORCID,Sun Hongqi¹²¹³¹⁴⁴^ORCID,Jiang San Ping¹²³⁴^ORCID,Johannessen Bernt¹⁵¹⁶⁴,Liu Shaomin¹²³⁴¹⁷^ORCID

Affiliation:

1. WA School of Mines: Minerals, Energy and Chemical Engineering

2. Curtin University

3. WA 6102

4. Australia

5. Eyring Materials Center

6. Arizona State University

7. Tempe

8. USA

9. School of Chemical Engineering

10. The University of Adelaide

11. Adelaide

12. School of Engineering

13. Edith Cowan University

14. WA 6027

15. Australian Synchrotron

16. Victoria 3168

17. Beijing Advanced Innovation Centre for Soft Matter Science and Engineering

Abstract

A Co single-atom catalyst on g-C₃N₄ support was prepared for the selective oxidation of ethylbenzene (EB) to acetophenone (AcPO) by peroxymonosulfate (PMS). The Co atoms bonded with N were robust active sites for EB oxidation via the radical pathway.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/TA/D0TA11503G

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1. Solvent-Free Oxidation of Primary Carbon-Hydrogen Bonds in Toluene Using Au-Pd Alloy Nanoparticles

2. Selective Hydrocarbon Oxidation in Zeolites

3. Copper-Catalyzed [2+2+2] Modular Synthesis of Multisubstituted Pyridines: Alkenylation of Nitriles with Vinyliodonium Salts