Chromium-catalyzed allylic defluorinative acylation of trifluoromethyl-substituted alkenes with acyl oxime esters-Reference-Cited by-同舟云学术

Chromium-catalyzed allylic defluorinative acylation of trifluoromethyl-substituted alkenes with acyl oxime esters

Published:2023 Issue:23 Volume:10 Page:5843-5850
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Shi Hongzhang¹,Dong Haiyan¹,Wang Chuan¹^ORCID

Affiliation:

1. Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China

Abstract

A chromium-catalyzed reductive allylic defluorinative acylation of trifluoromethyl-substituted alkenes with acyl oxime esters has been developed, allowing for efficient synthesis of various ketones bearing a gem-difluoroalkene unit.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO01331F

Reference79 articles.

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4. Fluoro-artemisinins: When a gem-difluoroethylene replaces a carbonyl group

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