Speciation of indium(iii) chloro complexes in the solvent extraction process from chloride aqueous solutions to ionic liquids-Reference-Cited by-同舟云学术

Speciation of indium(iii) chloro complexes in the solvent extraction process from chloride aqueous solutions to ionic liquids

Published:2017 Issue:13 Volume:46 Page:4412-4421
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Deferm Clio¹²³⁴⁵,Onghena Bieke¹²³⁴,Vander Hoogerstraete Tom¹²³⁴,Banerjee Dipanjan⁶⁷⁸⁹,Luyten Jan⁵¹⁰¹¹¹²⁴,Oosterhof Harald⁵¹⁰¹¹¹²⁴,Fransaer Jan¹¹³³⁴,Binnemans Koen¹²³⁴^ORCID

Affiliation:

1. KU Leuven

2. Department of Chemistry

3. B-3001 Heverlee

4. Belgium

5. Umicore

6. Dutch-Belgian Beamline (DUBBLE)

7. ESRF – The European Synchrotron

8. 38043 Grenoble Cedex 9

9. France

10. Group Research & Development

11. Competence Area Recycling and Extraction Technologies

12. B-2250 Olen

13. Department of Materials Engineering

Abstract

Indium(iii) exists as octahedral mixed complexes, [In(H₂O)_6−nCl_n]³⁻ⁿ (0 ≤ n ≤ 6), in acidic chloride media. After extraction, only the tetrahedral [InCl₄]⁻ complex is present in the ionic liquid phase.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00618G

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