One molecule of ionic liquid and tert-alcohol on a polystyrene-support as catalysts for efficient nucleophilic substitution including fluorination-Reference-Cited by-同舟云学术

One molecule of ionic liquid and tert-alcohol on a polystyrene-support as catalysts for efficient nucleophilic substitution including fluorination

Published:2014 Issue:45 Volume:12 Page:9264-9271
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Shinde Sandip S.¹²³,Patil Sunil N.¹²³

Affiliation:

1. Division of Organic Chemistry

2. National Chemical Laboratory (CSIR-NCL)

3. Pune 411008, India

Abstract

The tert-alcohol and ionic liquid solvents in one molecule [mim-^tOH][OMs] was immobilized on polystyrene and reported to be a highly efficient catalyst in aliphatic nucleophilic substitution using alkali metal salts.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB01781A

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2. Anodic Fluorination Based on Cation Exchange between Alkali-Metal Fluorides and Solid-Supported Acids

3. Bis-Terminal Hydroxy Polyethers as All-Purpose, Multifunctional Organic Promoters: A Mechanistic Investigation and Applications

4. Facile Nucleophilic Fluorination Reactions Using tert-Alcohols as a Reaction Medium: Significantly Enhanced Reactivity of Alkali Metal Fluorides and Improved Selectivity

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