Affiliation:
1. Department of Chemistry, Maharshi Dayanand University, Rohtak-124001, India
Abstract
Significant advancement in the preparation of fascinating fluoroorganics is highly desirable
in view of their limited natural occurrence and ever-increasing applications in medicinal and material
sciences. Ionic liquids act as the most promising green media for a variety of nucleophilic and electrophilic
fluorinations in terms of chemoselectivity, reaction yields, reusability, operational simplicity
and scalability. The use of these designer solvents in stimulating the electrified synthesis of fluorinated
compounds is also appreciable due to their tuneable electrochemical characteristics. Recent innovations
in fluorination techniques depict the substantial role of ionic liquids in fluorotransformations
such as the use of tagged ionic liquids in nucleophilic fluorinations, ionic liquid assisted biological
fluorination, enantioselective fluorinations using chiral electrophilic reagents along with ionic liquid
media, use of task-specific ionic liquids with mediators in electrochemical fluorinations and ionic liquid
promoted electrifying synthesis of medicinally important fluorinated heteroaromatics and radiopharmaceuticals.
Publisher
Bentham Science Publishers Ltd.
Subject
Organic Chemistry,Biochemistry
Cited by
4 articles.
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