A proton-conducting lanthanide metal–organic framework integrated with a dielectric anomaly and second-order nonlinear optical effect

Author:

Liang Xiaoqiang12345,Zhang Feng1234,Zhao Haixia6789,Ye Wei51011,Long Lasheng6789,Zhu Guangshan1234

Affiliation:

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry

2. College of Chemistry

3. Jilin University

4. Changchun 130012, PR China

5. College of Environmental and Chemical Engineering

6. State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry

7. College of Chemistry and Chemical Engineering

8. Xiamen University

9. Xiamen 361005, PR China

10. Xi'an Polytechnic University

11. Xi'an 710048, PR China

Abstract

A multifunctional metal–organic framework, {[Gd4(R-ttpc)2(R-Httpc)2(HCOO)2(H2O)8]·4H2O}n [JUC-125, R-H3ttpc = (3R,3′R,3′′R)-1,1′,1′′-(1,3,5-triazine-2,4,6-triyl)-tripiperidine-3-carboxylic acid], shows proton conduction, dielectric anomalous behaviour and a second-order NLO effect.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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