Water-assisted proton conduction regulated by hydrophilic groups in metallo-hydrogen-bonded organic frameworks: “like-attracts-like” between hydrophilic groups and water molecules

Author:

Wang Sen1,Xie Fengxia1,Zhang Shiwen1,Liang Xiaoqiang1ORCID,Gao Qianhang1,Chen Yu1,Zhang Feng2ORCID,Wen Chen3ORCID,Feng Lei3,Wan Chengan3

Affiliation:

1. College of Environmental and Chemical Engineering, Xi'an Polytechnic University, Xi'an 710048, PR China

2. Key Laboratory of Photochemical Biomaterials and Energy Storage Materials, Heilongjiang Province and College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, PR China

3. Beijing Spacecrafts, Beijing 100094, PR China

Abstract

The proton conductivities in two metallo-hydrogen-bonded frameworks (MHOFs) are highly influenced by the different hydrophilicities of hydrophilic groups in materials.

Funder

National Natural Science Foundation of China

Natural Science Basic Research Program of Shaanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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