Sulfur-containing stable five-membered “cycloallene” complexes: 1-thia-2-zircona- and 1-thia-2-titanacyclopenta-3,4-dienes-Reference-Cited by-同舟云学术

Sulfur-containing stable five-membered “cycloallene” complexes: 1-thia-2-zircona- and 1-thia-2-titanacyclopenta-3,4-dienes

Published:2015 Issue:6 Volume:2 Page:681-687
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Suzuki Noriyuki¹²³⁴⁵,Asada Takumi¹²³⁴⁵,Kawamura Akiko¹²³⁴⁵,Masuyama Yoshiro¹²³⁴⁵

Affiliation:

1. Department of Materials and Life Sciences

2. Faculty of Science and Technology

3. Sophia University

4. Tokyo 102-8554

5. Japan

Abstract

Stable five-membered sulfur-containing metallacyclic allenes, 1-thia-2-metallacyclopenta-3,4-diene, were synthesized from the reactions of low-valent zirconocene or titanocene with alkynylthioamides.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/QO/C5QO00072F

Reference44 articles.

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2. M. Ogasawara , in Cumulenes and Allenes, Science of Synthesis, ed. N. Krause, Thieme, Stuttgart, 2007, pp. 9–70

3. The first generation and trapping of a five-membered ring allene: 2-dehydro-3a,4,5,6,6a-pentahydropentalene

4. Evidence for the formation of a New Five-Membered Ring Cyclic Allene: Generation of 1-Cyclopenta-1,2-Dien-1-Ylbenzene

5. Syntheses and structure of 8-, 7-, and 6-membered silacycloallenes

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