Induced phosphorescence from Pt → Ag and Ag(i)⋯Ag(i) metallophilic interactions in benzenedithiolatodiimine-Pt2/Ag2 clusters: a combined experimental and theoretical investigation

Author:

Moussa Jamal12345,Chamoreau Lise Marie12345,Gullo Maria Pia6789,Degli Esposti Alessandra6789,Barbieri Andrea6789,Amouri Hani12345

Affiliation:

1. Sorbonne Universités

2. UPMC Univ Paris 06

3. Université Pierre et Marie Curie

4. Institut Parisien de Chimie Moléculaire (IPCM) UMR 8232

5. 75252 Paris Cedex 05

6. Istituto per la Sintesi Organica e la Fotoreattività (ISOF)

7. Consiglio Nazionale delle Ricerche (CNR)

8. 40129 Bologna

9. Italy

Abstract

We report the synthesis and luminescence properties of a novel platinum(ii)–silver(i) cluster exhibiting supramolecular donor–acceptor dative Pt → Ag bonds as well as d10⋯d10 argentophilic interactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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