Cyclometalated luminescent platinum(<scp>ii</scp>) complexes of dissymmetrical 2,2′:4′,2′′-terpyridine and its self-assembled dimer presenting Pt

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Cyclometalated luminescent platinum(ii) complexes of dissymmetrical 2,2′:4′,2′′-terpyridine and its self-assembled dimer presenting Pt–Ag dative bonds

Published:2024 Issue:30 Volume:53 Page:12477-12485
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Benda Lorien¹,Miton Louise¹^ORCID,Hadj Seyd Nihal¹,Chamoreau Lise-Marie¹,Jonusauskas Gediminas²^ORCID,McClenaghan Nathan D.³^ORCID,Hasenknopf Bernold¹^ORCID,Marvaud Valérie¹^ORCID,Vives Guillaume¹^ORCID

Affiliation:

1. Sorbonne Université, UMR CNRS 8232, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, 75005, Paris, France

2. Univ. Bordeaux, CNRS, LOMA, UMR 5798, F-33400 Talence, France

3. Univ. Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, F-33400 Talence, France

Abstract

A novel dissymmetrical terpyridine ligand was synthesized and used to prepare luminescent cyclometalated platinum complexes and a self-assembled helical dimer stabilized by metallophilic Pt–Ag interactions.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01153H

Reference60 articles.

1. 3. Dehydrogenation of pyridine by anhydrous ferric chloride

2. Syntheses of Functionalized 2,2′:6′,2′′‐Terpyridines

3. Synthesis of 4′-Substituted-2,2′:6′,2′′-Terpyridines

4. Metal‐Terpyridine Complexes in Catalytic Application – A Spotlight on the Last Decade

5. Terpyridine-based metallosupramolecular constructs: tailored monomers to precise 2D-motifs and 3D-metallocages

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