Using the nature of the achiral solvent to orient chiral resolution-Reference-Cited by-同舟云学术

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Using the nature of the achiral solvent to orient chiral resolution

Published:2024 Issue:15 Volume:26 Page:2056-2059
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

de Meester Joséphine¹,Shemchuk Oleksii¹,Collard Laurent¹,Wouters Johan²,Baillieux Simon¹,Robeyns Koen¹^ORCID,Leyssens Tom¹^ORCID

Affiliation:

1. Institute of Condensed Matter and Nanosciences, UCLouvain, Place Louis Pasteur 1, 1348 Louvain-la-Neuve, Belgium

2. Department of Chemistry, Université de Namur, UNamur, Rue de Bruxelles 61, 5000 Namur, Belgium

Abstract

Both (R)- and (S)-Binol can be resolved from a racemic mixture using the same (R,R)-diamine resolving agent, merely adapting the nature of the solvent. This peculiarity is explained by the existence of both a diastereomeric as well as enantiospecific solvate cocrystal system.

Funder

Fonds De La Recherche Scientifique - FNRS

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CE/D4CE00124A

Reference31 articles.

1. Chiral Drugs. An Overview

2. Recent advances in the field of chiral crystallization

3. Design of diastereomeric salt resolution via multicomponent system characterization: a case study with hydrate formation

4. The Growing Importance of Chirality in 3D Chemical Space Exploration and Modern Drug Discovery Approaches for Hit-ID

5. The market of chiral drugs: Chiral switches versus de novo enantiomerically pure compounds

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