Na6Sn3P4S16: Sn(<scp>ii</scp>)-chelated PS4 groups inspired an ultra-strong SHG response-Reference-Cited by-同舟云学术

Na₆Sn₃P₄S₁₆: Sn(ii)-chelated PS₄ groups inspired an ultra-strong SHG response

Published:2023 Issue:19 Volume:10 Page:5726-5733
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhao Chenyao¹,Zhang Bingbing¹,Tian Xinyu¹,Zhou Guoqiang¹^ORCID,Xu Jingjing¹,Wu Kui²^ORCID

Affiliation:

1. College of Chemistry and Materials Science, Hebei University, Baoding, China

2. State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan, China

Abstract

Na6Sn3P4S16 IR NLO thiophosphate exhibiting ultra-strong SHG response is originated from the collaborative polarization of edge-sharing SnS4 and PS4 units.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hebei Province

Science Fund for Distinguished Young Scholars of Hebei Province

Hebei University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D3QI01257C

Reference65 articles.

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2. [ASr₄Cl][Ge₃S₁₀] (A = Na, K) and [KBa₄Cl][Ge₃S₁₀]: new salt-inclusion infrared nonlinear optical crystals with zero-dimensional [Ge₃S₉] clusters

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4. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

5. First polar quaternary sulphide CsLiGa₆S₁₀ with mixed ordered alkali cations displaying excellent infrared nonlinear optical properties

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