RbPbPS4: a promising IR nonlinear optical material achieved by lone-pair-cation-substitution-induced structure transformation

Author:

Wang A-Yang123,Zhou Sheng-Hua14,Ran Mao-Yin125,Li Bingxuan12,Wu Xin-Tao12ORCID,Lin Hua12ORCID,Zhu Qi-Long12ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

2. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, Fujian 350108, China

3. College of Chemistry, Fuzhou University, Fuzhou 350002, China

4. Resource environment & Clean energy Laboratory, School of Chemistry and Chemical Engineering, Jiangsu University of Technology 213001, China

5. University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A novel excellent IR-NLO material RbPbPS4 with superior comprehensive performances is provided, representing the first quaternary Pb-based chalcogenide breaks through the incompatibility between a large Eg and a strong deff.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Fujian Province

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

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