Gold catalysed site-selective cross-coupling of tertiary α-silylamines with 1-iodoalkynes under UVA LED light-Reference-Cited by-同舟云学术

Gold catalysed site-selective cross-coupling of tertiary α-silylamines with 1-iodoalkynes under UVA LED light

Published:2023 Issue:3 Volume:10 Page:759-766
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhao Yichao¹^ORCID,Merrett James Theodore¹,Jin Jianwen¹^ORCID,Yu Li-Juan²^ORCID,Coote Michelle Louise³^ORCID,Chan Philip Wai Hong⁴¹^ORCID

Affiliation:

1. School of Chemistry, Monash University, Clayton, Victoria, 3800, Australia

2. Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, 2601, Australia

3. Institute for Nanoscale Science and Technology, College of Science and Engineering, Flinders University, South Australia, 5042, Australia

4. Department of Biological Environment, Jiyang College of Zhejiang A&F University, Zhuji, 311800, China

Abstract

A synthetic method that relies on a gold(i,i) complex and UVA LED light source to catalyse the α-alkynylation of tertiary α-silylamines by 1-iodoalkynes is described.

Funder

Zhejiang A and F University

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D2QO01581A

Reference56 articles.

1. Merging Visible Light Photoredox and Gold Catalysis

2. Gold‐Catalyzed Cross‐Coupling Reactions: An Overview of Design Strategies, Mechanistic Studies, and Applications

3. Insights into the Mechanism of Gold(I) Oxidation with Aryldiazonium Salts

4. Homogeneous Gold Redox Chemistry: Organometallics, Catalysis, and Beyond

5. Light in Gold Catalysis

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