Thiourea as a precatalyst for the electron donor–acceptor complex photoactivation platform of oxime esters

Author:

Mao Haichen1,Zhang Yuting1,Cao Hengrong1,Shi Qianqian1,Lan Yu1ORCID,Chang Junbiao1,Zhu Bo1ORCID

Affiliation:

1. State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, NMPA Key Laboratory for Research and Evaluation of Innovative Drug, Henan Key Laboratory of Organic Functional Molecule and Drug Innovation, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China

Abstract

A novel electron donor–acceptor (EDA) complex catalysis strategy has been developed using thiourea as a precatalyst under blue LED irradiation. Using 2–5 mol% of thiourea, various nitrogen-containing compounds were successfully synthesized.

Funder

National Natural Science Foundation of China

Central Plains Scholars and Scientists Studio Fund

Natural Science Foundation of Henan Province

Publisher

Royal Society of Chemistry (RSC)

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