A study combining magic-angle spinning NMR and small-angle X-ray scattering on the interaction in the mixture of poly(benzyl methacrylate) and ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide-Reference-Cited by-同舟云学术

A study combining magic-angle spinning NMR and small-angle X-ray scattering on the interaction in the mixture of poly(benzyl methacrylate) and ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide

Published:2022 Issue:43 Volume:24 Page:26575-26582
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Morita Takeshi¹^ORCID,Okada Hitomi²,Yamada Taisei¹,Hidaka Ryo²,Ueki Takeshi³⁴^ORCID,Niitsuma Kazuyuki⁵,Kitazawa Yuzo⁵^ORCID,Watanabe Masayoshi⁵⁶^ORCID,Nishikawa Keiko¹⁷^ORCID,Higashi Kenjirou²^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science, Chiba University, Chiba, 263-8522, Japan

2. Graduate School of Pharmaceutical Sciences, Chiba University, Chiba, 260-8675, Japan

3. Research Center for Functional Materials, National Institute for Materials Science (NIMS), Tsukuba, Ibaraki, 305-0044, Japan

4. Graduate School of Life Science, Hokkaido University, Sapporo, 060-0810, Japan

5. Department of Chemistry and Biotechnology, Yokohama National University, Yokohama, 240-8501, Japan

6. Institute of Advanced Sciences, Yokohama National University, Yokohama, 240-8501, Japan

7. Toyota Physical & Chemical Research Institute, Nagakute, Aichi, 480-1192, Japan

Abstract

Despite being an LCST system, the NMR results indicate that the number of ionic liquid ions interacting with the solute polymer increases even at temperatures approaching the separation line.

Funder

Japan Society for the Promotion of Science

Chiba University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP02207A

Reference50 articles.

1. Lower Critical Solution Temperature Behavior of Linear Polymers in Ionic Liquids and the Corresponding Volume Phase Transition of Polymer Gels

2. Macromolecules in Ionic Liquids: Progress, Challenges, and Opportunities

3. Stimuli-responsive polymers in ionic liquids

4. Difference in Lower Critical Solution Temperature Behavior between Random Copolymers and a Homopolymer Having Solvatophilic and Solvatophobic Structures in an Ionic Liquid

5. Thermodynamic study on phase transitions of poly(benzyl methacrylate) in ionic liquid solvents

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